Ika Fitri Ulfindrayani, Irmina Kris Murwani, Eko Sri Kunarti, Afifah Rosyidah, Harsasi Setyawati, Qurrota A’yuni, Abdul Wafi, Eka Cahya Muliawati
The catalysts MgF2 supported ZnO (0; 2.5; 5; 7.5; 10 and 15% w/w) were synthesized by sol-gel method. The structure of the catalysts were characterized by XRD. The acidity of the catalyst determined by pyridine-FTIR method showed that 7.5% ZnO/MgF2 had the highest acidity. The surface area of the ZnO/MgF2 was measured by N2 adsorption-desorption method. The surface area of the ZnO/MgF2 catalysts decrease with the increase in Zn content. The measurement SBET of the catalysts was in range of 5.31 to 9.44 m2/g. The morphology of the catalyst was observed by Scanning Electron Microscope (SEM). The synthesized catalysts performance was tested in phenol acylation and were determined by High Performance Liquid Chromatography (HPLC), which the main products were p-HAP (hydroxyacetophenone) and PA (phenyl acetate). The formation of p-HAP was influenced by the Lewis acid site, while PA was influenced by the Brønsted acid site. The highest conversion was achieved 85.36% by 7.5% ZnO/MgF2, while the yields of the p-HAP and PA were 56.06 and 23.40% respectively. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2025.
Postgraduate School, Universitas Negeri Surabaya, Surabaya, 60213, Indonesia; Department of Chemistry, Faculty of Sains and Analytica Data, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, 55281, Indonesia; Department of Chemistry, Faculty of Science and Technology, Universitas Airlangga, Surabaya, 60115, Indonesia; Department of Chemistry, Faculty of Science, Hacettepe University, Beytepe, Ankara, 06800, Turkey; Research Center for Food Technology and Processing, National Research and Innovation Agency (BRIN), Gunungkidul, Yogyakarta, 55861, Indonesia; Chemical Engineering, Faculty of Industrial Technology, Institut Teknologi Adhi Tama Surabaya, Arief Rahman Hakim St. Number 100, Surabaya, 60117, Indonesia
