The Influence of Precursor to Activator Ratio and Curing Temperature on Geopolymer Paste with One-Part Method

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Ari Widayanti, Januarti J. Ekaputri, Iqlima N. Amini, Himawan T. B. M. Petrus, Anandita Ade Putri, Ria A. A. Soemitro, Anjas Handayani

2025 Civil Engineering Journal (Iran) Vol. 11 Issue 7 Article Cited by 10 Quartile

Abstract

Geopolymer is an eco-friendly material that serves as a sustainable alternative to Portland cement in construction. This binder reduces carbon dioxide emissions from cement production. However, its manufacturing process remains complex and requires professional expertise. This study explores an environmentally friendly cement produced through the “One-Part Method” (or the “just add water” method), which simplifies geopolymer application, making it as user-friendly as Portland cement. However, research on the performance of one-part geopolymers with varying activator contents and curing temperatures remains limited. In this study, Class F fly ash was used as a precursor, combined with a dry activator made from geothermal sludge and sodium hydroxide (NaOH). Two compositions were tested with precursor-to-dry activator ratios of 5:1 (OPG-F5F) and 7:1 (OPG-F7F). The compressive strength was significantly influenced by the Si/Al, Na/Si, Na/Al, and water/solid ratios derived from the precursor and activator. Mechanical properties were analyzed at three curing temperatures: ambient, 40°C, and 60°C. Results showed that OPG-F7F achieved the highest strength at 60°C, reaching 76.1 MPa at 28 days. Mineral analysis before and after steam curing revealed no changes in composition, while morphological analysis indicated that higher temperatures produced a denser geopolymer matrix. These findings demonstrate the strong potential of geopolymer cement as a viable Portland cement replacement using the One-Part Method. © 2025 by the authors.

Affiliations

Department of Transportation Engineering, Universitas Negeri Surabaya, Kampus UNESA Ketintang, Surabaya, 60231, Indonesia; Department of Civil Engineering, Faculty of Civil, Planning and Geo Engineering, Institut Teknologi Sepuluh Nopember, Kampus ITS, Sukolilo, Surabaya, 60111, Indonesia; Department of Civil Engineering, Universitas Negeri Surabaya, Kampus UNESA Ketintang, Surabaya, 60231, Indonesia; Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, 55281, Indonesia; Department of Business Management, Faculty of Creative Design and Digital Business, Institut Teknologi Sepuluh Nopember, Kampus ITS, Sukolilo, Surabaya, 60111, Indonesia; PT. Semen Indogreen Sentosa (HKSIS), Tegalsari, Surabaya, 60265, Indonesia